SnCl4-mediated reaction of ozonides with allyltrimethylsilane: formation of 1,2-dioxolanes

Authors
Dussault, PH Liu, XJ
Citation
Ph. Dussault et Xj. Liu, SnCl4-mediated reaction of ozonides with allyltrimethylsilane: formation of 1,2-dioxolanes, TETRAHEDR L, 40(36), 1999, pp. 6553-6556
Citations number
16
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
00404039 → ACNP
Volume
40
Issue
36
Year of publication
1999
Pages
6553 - 6556
Database
ISI
SICI code
0040-4039(19990903)40:36<6553:SROOWA>2.0.ZU;2-W
Abstract
SnCl4-mediated reaction of ozonides (1,2,4-trioxolanes) with allyltrimethyl silane furnishes trimethylsilylmethyl-1,2-dioxolanes via metalated carbonyl oxides. The carbonyl oxides can arise through initial ionization of either the ether or peroxide oxygens. (C) 1999 Elsevier Science Ltd. All rights r eserved.