Novel diastereoselective allene formation by an ene reaction of significantly twisted 1,3-dienes with singlet oxygen

Authors
Mori, H Matsuo, T Yamashita, K Katsumura, S
Citation
H. Mori et al., Novel diastereoselective allene formation by an ene reaction of significantly twisted 1,3-dienes with singlet oxygen, TETRAHEDR L, 40(35), 1999, pp. 6461-6464
Citations number
7
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
00404039 → ACNP
Volume
40
Issue
35
Year of publication
1999
Pages
6461 - 6464
Database
ISI
SICI code
0040-4039(19990827)40:35<6461:NDAFBA>2.0.ZU;2-M
Abstract
The highly diastereoselective allene formation by photosensitized oxygenati on of the significantly twisted novel 1,3-dienes which possess an sp(3) chi ral center due to a secondary hydroxy group and a tertiary alkoxy group at allylic positions is described. (C) 1999 Elsevier Science Ltd. All rights r eserved.