Molecular structure of a mu-oxo chromium-iron complex: Rare example of a crystallographically characterized mu-oxo heterometallic porphyrin

Authors
Oyaizu, K Haryono, A Nishimura, Y Yamamoto, K Tsuchida, E
Citation
K. Oyaizu et al., Molecular structure of a mu-oxo chromium-iron complex: Rare example of a crystallographically characterized mu-oxo heterometallic porphyrin, B CHEM S J, 72(8), 1999, pp. 1781-1784
Citations number
25
Categorie Soggetti
Chemistry
Journal title
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN
ISSN journal
00092673 → ACNP
Volume
72
Issue
8
Year of publication
1999
Pages
1781 - 1784
Database
ISI
SICI code
0009-2673(199908)72:8<1781:MSOAMC>2.0.ZU;2-5
Abstract
The crystal structure of a mu-oxo heterometallic porphyrin [(pip)(tpp)(CrOF eIII)-O-III(tpp)] (pip = piperidine) not only confirmed the proposed oxidat ion state of chromium and iron atoms, but also revealed a unique coordinati on environment around chromium(III), which is substantially protruded from the porphyrin plane.