Carbonylation of formaldehyde with carbon monoxide over cation-exchange resin catalysts

Authors
Wang, ZB Shimada, T Takagi, H Ahn, CH Sano, T Soga, K Takahashi, I Masuda, T
Citation
Zb. Wang et al., Carbonylation of formaldehyde with carbon monoxide over cation-exchange resin catalysts, B CHEM S J, 72(8), 1999, pp. 1935-1940
Citations number
18
Categorie Soggetti
Chemistry
Journal title
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN
ISSN journal
00092673 → ACNP
Volume
72
Issue
8
Year of publication
1999
Pages
1935 - 1940
Database
ISI
SICI code
0009-2673(199908)72:8<1935:COFWCM>2.0.ZU;2-X
Abstract
The carbonylation of formaldehyde with carbon monoxide was carried out over two kinds of cation-exchange resins as solid acid catalysts. Effects of re action conditions on the catalytic performance were studied. From H-1 NMR, C-13 NMR, IR, and GC-MS analyses of the products obtained, ii. was found th at 1,3-dioxolan-4-one (1,3-DOX-4) is selectively produced over the cation-e xchange resins. The carbonylation of formaldehyde with carbon monoxide over the cation-exchange resins proceeds under milder reaction conditions, as c ompared with HZSM-5 zeolite.