Absolute elastic differential cross-sections for electron scattering by N2O at 1.5-100 eV

Citation
M. Kitajima et al., Absolute elastic differential cross-sections for electron scattering by N2O at 1.5-100 eV, CHEM P LETT, 309(5-6), 1999, pp. 414-420
Citations number
23
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
CHEMICAL PHYSICS LETTERS
ISSN journal
00092614 → ACNP
Volume
309
Issue
5-6
Year of publication
1999
Pages
414 - 420
Database
ISI
SICI code
0009-2614(19990820)309:5-6<414:AEDCFE>2.0.ZU;2-X
Abstract
Absolute differential cross-sections (DCS) for elastic electron scattering by N2O have been measured by a crossed-beam experiment with impact energies ranging from 1.5 to 100 eV and angles between 20 degrees and 130 degrees; DCS below 5 eV have been observed. A clear p-wave structure is observed for the first time in the DCS at 2.2 eV where a narrow intense shape resonance has been reported. A continuum multiple scattering (CMS) calculation has a lso been carried out. The CMS results and the reported theoretical DCS show much larger deviations near 5 eV than those at 2.2 eV from the present exp erimental values, indicating that an approximation of higher quality is nee ded to account for the DCS in the non-resonant region. (C) 1999 Elsevier Sc ience B.V. All rights reserved.