Synthesis and crystal structure of new sulfate-bridged coordination polymer, {(4,4 '-bpyH(2))[Fe-3(4,4 '-bpy)(3)(SO4)(4)(H2O)(6)]center dot 10H(2)O}(n) (4,4 '-bpy=4,4 '-bipyridine). Three-dimensional network with microporouschannels

Authors
Noro, S Kondo, M Kitagawa, S Ishii, T Matsuzaka, H
Citation
S. Noro et al., Synthesis and crystal structure of new sulfate-bridged coordination polymer, {(4,4 '-bpyH(2))[Fe-3(4,4 '-bpy)(3)(SO4)(4)(H2O)(6)]center dot 10H(2)O}(n) (4,4 '-bpy=4,4 '-bipyridine). Three-dimensional network with microporouschannels, CHEM LETT, (8), 1999, pp. 727-728
Citations number
12
Categorie Soggetti
Chemistry
Journal title
CHEMISTRY LETTERS
ISSN journal
03667022 → ACNP
Issue
8
Year of publication
1999
Pages
727 - 728
Database
ISI
SICI code
0366-7022(199908):8<727:SACSON>2.0.ZU;2-A
Abstract
A new sulfate-bridged coordination polymer, {(4,4'-bpyH(2))[Fe-3(4,4'-bpy)( 3)(SO4)(4)(H2O)(6)]. 10H(2)O}(n), was synthesized and crystallographically characterized. This complex shows a novel three-dimensional (3-D) log-cabin type structure constructed from one-dimensional (1-D) [Fe(4,4'-bpy)(H2O)(2 )](n) cationic chain, free protonated 4,4'-bpy, and sulfate dianion. This s tructure shows channel-like cavities with dimensions of about 3 Angstrom x 4 Angstrom.