Photoelectron emission from Au was measured in ambient atmosphere under irr
adiation of ultraviolet light from a Hg lamp. The emission was greatly infl
uenced by the adsorption of organic and inorganic vapors. The adsorption of
cyclohexene showed a significant, but gradual increase of photoelectron em
ission. On the other hand, the adsorption of acetone reduced photoelectron
emission irreversibly to near zero. The change of the photoelectron emissio
n could be interpreted in terms of the change of the work function.