Synthesis and X-ray structures of arsenic(V) porphyrins with symmetric diaxial ligands of Me-2 and F-2

Authors
Yasumoto, M Satoh, W Nadano, R Yamamoto, Y Akiba, K
Citation
M. Yasumoto et al., Synthesis and X-ray structures of arsenic(V) porphyrins with symmetric diaxial ligands of Me-2 and F-2, CHEM LETT, (8), 1999, pp. 791-792
Citations number
11
Categorie Soggetti
Chemistry
Journal title
CHEMISTRY LETTERS
ISSN journal
03667022 → ACNP
Issue
8
Year of publication
1999
Pages
791 - 792
Database
ISI
SICI code
0366-7022(199908):8<791:SAXSOA>2.0.ZU;2-D
Abstract
Arsenic porphyrins [(TPP)As(Me)(2)]+PF6- (2-PF6), [(TPP)As(F)(2)]+PF6+ (3-P F6), and [(OEP)As(F)(2)]+PF6- (4-PF6) were prepared and the X-ray crystallo graphic structures revealed that the axial ligand and the porphyrin core af fected to control the conformation of the porphyrins.