Transient spectra and photoreaction of 4-methoxybenzoyloxyl radical

Authors
Oishi, S Tsubaki, H Matsuzawa, H
Citation
S. Oishi et al., Transient spectra and photoreaction of 4-methoxybenzoyloxyl radical, CHEM LETT, (8), 1999, pp. 805-806
Citations number
9
Categorie Soggetti
Chemistry
Journal title
CHEMISTRY LETTERS
ISSN journal
03667022 → ACNP
Issue
8
Year of publication
1999
Pages
805 - 806
Database
ISI
SICI code
0366-7022(199908):8<805:TSAPO4>2.0.ZU;2-U
Abstract
An absorption maximum and a molar extinction coefficient of a transient in the laser flash photolysis of bis(4-methoxybenzoyl) peroxide were determine d as 900 nm and 750 M(-1)cm(-1), respectively. The comparison of products f or the photolysis at 266 nm with and without 1064-nm pulse gave a solid evi dence of 4-methoxybenzoyloxyl radical being responsible for the absorption.