The crystal structure and magnetic properties of Cu-II-Ni-II heterodinuclear complex with N,N '-bis(2-pyridyl-ethyl)-oxamide dianion

Authors
Liu, B Liao, DZ Jiang, ZH Yan, SP Wang, GL Yao, XK Wang, HG
Citation
B. Liu et al., The crystal structure and magnetic properties of Cu-II-Ni-II heterodinuclear complex with N,N '-bis(2-pyridyl-ethyl)-oxamide dianion, CHEM LETT, (8), 1999, pp. 819-820
Citations number
16
Categorie Soggetti
Chemistry
Journal title
CHEMISTRY LETTERS
ISSN journal
03667022 → ACNP
Issue
8
Year of publication
1999
Pages
819 - 820
Database
ISI
SICI code
0366-7022(199908):8<819:TCSAMP>2.0.ZU;2-0
Abstract
A new Cu-II-Ni-II heterodinuclear complex [Cu(PEoxd) Ni(bpy)(2)](ClO4)(2). 1/2H(2)O has been synthesized and its structure determined by single crysta l X-ray analysis. Crystal data: space group P2(1)/c with a = 9.226(2) Angst rom, b = 30.857(6) Angstrom, c = 14.241(3) Angstrom, and beta = 97.36(3)deg rees, V = 4021(2) Angstrom(3), Z = 4. Magnetic measurement indicates that t he overall magnetic behavior is weakly antiferromagnetic.