Diastereo-differentiation during 2,4-pentanediol tethered Simmons-Smith type cyclopropanation: Reaction species of hydroxyl group directed zinc carbenoid addition

Authors
Sugimura, T Yoshikawa, M Mizuguchi, M Tai, A
Citation
T. Sugimura et al., Diastereo-differentiation during 2,4-pentanediol tethered Simmons-Smith type cyclopropanation: Reaction species of hydroxyl group directed zinc carbenoid addition, CHEM LETT, (8), 1999, pp. 831-832
Citations number
17
Categorie Soggetti
Chemistry
Journal title
CHEMISTRY LETTERS
ISSN journal
03667022 → ACNP
Issue
8
Year of publication
1999
Pages
831 - 832
Database
ISI
SICI code
0366-7022(199908):8<831:DD2TST>2.0.ZU;2-3
Abstract
The predominant formation methods for the diastereodifferentiating species of zinc carbenoid addition to the 1-cyclohexenyl ether carrying the 2,4-pen tanediol moiety were established. The species were found to include two zin c atoms and one carbenoid carbon at the hydroxyl group.