Zy. Wang et Km. Cheng, THE HYDROCARBON GENERATION MECHANISM AND THE 3-STAGE TYPE MODEL OF HYDROCARBON GENERATION FOR CARBONATE SOURCE ROCKS, SCIENCE IN CHINA SERIES D-EARTH SCIENCES, 40(3), 1997, pp. 232-238
The diagenetic mechanism and process of carbonate rocks, which is diff
erent to that of clastic rocks, decides the existence of different exi
sting state organic matters in carbonate rocks. This has been verified
by both the microscopic observation of organic petrology and the anal
ysis of organic geochemistry of many samples. Based on the hydrous pyr
olysis simulation experiment of the low-mature carbonate rocks, the co
ntrasting study on the yield and their geochemistry characteristics of
different existing state soluble organic matters of a series of vario
us maturity samples shows that the different existing slate organic ma
tters make different contributions to hydrocarbon generation during ev
ery evolution state. So that, the hydrocarbon generation process of ca
rbonate rocks can be summarized as the following three stages: the fir
st is the direct degradation of biogenic bitumen macromolecules during
the immature stage, the second is the thermal degradation of a large
amount of kerogen at the mature stage, the last stage is the expulsion
or release of inclusion organic matter owing to the increased thermal
expansion pressure during the high evolution stage.