Iminoacylation 2. Addition of alkylated hydroxylamines via oxygen to platinum(IV)-bound nitriles

Authors
Wagner, G Pombeiro, AJL Kukushkin, YN Pakhomova, TB Ryabov, AD Kukushkin, VY
Citation
G. Wagner et al., Iminoacylation 2. Addition of alkylated hydroxylamines via oxygen to platinum(IV)-bound nitriles, INORG CHIM, 292(2), 1999, pp. 272-275
Citations number
16
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANICA CHIMICA ACTA
ISSN journal
00201693 → ACNP
Volume
292
Issue
2
Year of publication
1999
Pages
272 - 275
Database
ISI
SICI code
0020-1693(19990915)292:2<272:I2AOAH>2.0.ZU;2-U
Abstract
Addition of R2NOH (R = Me, Et, CH2Ph) to the acetonitrile ligands in the pl atinum(IV) complex trans-[PtCl4(MeCN)(2)] leads to unprecedented O-iminoacy lation of the dialkylhydroxylamines to produce trans-[PtCl4(NH=(Me)C-ONR2)( 2)]. (C) 1999 Elsevier Science S.A. All rights reserved.