We report the results of an extensive experimental investigation on the vel
ocity of rise of air bubbles in the size range d(b) = 3 - 80 mm in water. M
easurements were made in columns with inside diameters D-T = 0.01, 0.02, 0.
03, 0.051, 0.1, 0.174 and 0.63 m. The column diameter was found to have a s
ignificant effect on the rise velocity of the bubbles. When the ratio of th
e bubble diameter to the column diameter, d(b)/D-T, is smaller than 0.125 t
he influence of the column diameter on the rise velocity is negligible and
the rise velocity is described quite accurately by the Mendelson equation.
With increasing d(b)/D-T there is a significant reduction of the rise veloc
ity, i.e. there is a significant "wall effect". The wall effect for spheric
al cap bubbles rising in inviscid flow, obtained for bubble diameters large
r than 0.017 m, is described adequately by the Collins relation. The wall e
ffect for bubbles smaller than 0.017 m is described by an empirical relatio
n suggested by Clift, Grace and Weber. (C) 1999 Elsevier Science Ltd.