Molecular constants and Rydberg-Klein-Rees (RKR) potential curve for the Na-2 1(3)Sigma(-)(g) state

Authors
Liu, YM Li, JA Chen, DY Li, L Jones, KM Ji, B Le Roy, RJ
Citation
Ym. Liu et al., Molecular constants and Rydberg-Klein-Rees (RKR) potential curve for the Na-2 1(3)Sigma(-)(g) state, J CHEM PHYS, 111(8), 1999, pp. 3494-3497
Citations number
30
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF CHEMICAL PHYSICS
ISSN journal
00219606 → ACNP
Volume
111
Issue
8
Year of publication
1999
Pages
3494 - 3497
Database
ISI
SICI code
0021-9606(19990822)111:8<3494:MCAR(P>2.0.ZU;2-U
Abstract
Transitions into the doubly excited Na-2 1 (3)Sigma(g)(-) state have been a nalyzed using near-dissociation expansions (NDE) to represent the vibration al energies and inertial rotational constants, while the centrifugal distor tion constants were held fixed at "mechanically consistent" values calculat ed from the Rydberg-Klein-Rees (RKR) potential implied by those G(upsilon) and B-upsilon functions. The input data cover the range upsilon = 0 to 57 a nd N up to 47, and the fit yields upsilon(D) = 61.41(+/- 0.10) and D-0 = 33 85.70(+/- 0.2) cm(-1). (C) 1999 American Institute of Physics. [S0021-9606( 99)01031-4].