Polythiophenes are a very versatile class of conjugated polymers. Substitut
ed polythiophenes can be tailored for various applications by designing the
side groups to give the polymer different desired properties. Our work on
preparing polythiophenes designed to have high stability in the doped state
is described. We also discuss our efforts on tuning the colour of the emis
sion from polythiophenes for use in polymer light-emitting diodes. Design c
riteria for the synthesis of polythiophenes with high luminescence efficien
cy for use in light-emitting diodes and lasers are also described. Finally,
the design of polythiophenes for use in photodiodes is discussed.