The sound velocity was measured to investigate the polymerization transitio
n in the liquid S-Se alloy. The onset temperature, T-lambda, of polymerizat
ion transition could be found up to 10 at.% of Se, which decreases with inc
reasing Se fraction at the rate of -5.5 +/- 0.6 (K/at.%). The results indic
ate that T-lambda in liquid Se may not be observed in a finite temperature
range in contradiction to the previous theoretical calculation. (C) 1999 El
sevier Science B.V. All rights reserved.