Two-step relaxation in a viscous metallic liquid

Citation
A. Meyer et al., Two-step relaxation in a viscous metallic liquid, J NON-CRYST, 250, 1999, pp. 116-119
Citations number
16
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science
Journal title
JOURNAL OF NON-CRYSTALLINE SOLIDS
ISSN journal
00223093 → ACNP
Volume
250
Year of publication
1999
Part
1
Pages
116 - 119
Database
ISI
SICI code
0022-3093(199908)250:<116:TRIAVM>2.0.ZU;2-M
Abstract
We have studied the microscopic dynamics of the bulk glass forming alloy Zr 46.8Ti8.2Cu7.5Ni10Be27.5 with quasi-elastic neutron scattering. In contrast to simple metals the equilibrium liquid has a two-step structural relaxati on as do other liquids in their supercooled state. The fast beta-relaxation is in quantitative agreement with the scaling function of mode-coupling th eory, with a crossover temperature, T-c, some 50% greater than the caloric glass transition temperature. The longer time alpha-relaxation reveals a fa ilure of the Stokes-Einstein relation. (C) 1999 Elsevier Science B.V. All r ights reserved.