Formation and characteristics of Cu colloids from CuO powder by laser irradiation in 2-propanol

The laser ablation technique has been employed to prepare Cu colloids from CuO powder in 2-propanol using wavelengths of 1064 and 532 nm. The copper c olloids resulting from 1064 nm irradiation were conspicuously stable under aerobic conditions without any protective agent present. In addition to Cu particles, the formation of oxidized product, acetone, from 2-propanol was detected by gas chromatography. The discrepancy in the Cu colloidal formati on between 1064 and 532 nm was analyzed on the basis of the absorptive abil ity of CuO powder, the results of the power dependence, and the measurement s of the dose effect. The process of photoinduced coalescence that formed l arger spherical particles was found to be wavelength-dependent. The stabili ty of the Cu colloids could be the result of their near-perfect spherical s hape and the effect of their larger size.