Deposition and characterization of CdxHg1-xTe films electroplated from a nonaqueous bath

Citation
Jp. Nair et al., Deposition and characterization of CdxHg1-xTe films electroplated from a nonaqueous bath, J PHYS CH S, 60(10), 1999, pp. 1693-1703
Citations number
15
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science
Journal title
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS
ISSN journal
00223697 → ACNP
Volume
60
Issue
10
Year of publication
1999
Pages
1693 - 1703
Database
ISI
SICI code
0022-3697(199910)60:10<1693:DACOCF>2.0.ZU;2-W
Abstract
This paper presents the nonaqueous electrodeposition and characterisation o f CdxHg1-xTe films. Cyclic voltammetry and photovoltammetry were used to id entify the potential for CdxHg1-xTe deposition. Film composition and struct ure were analysed using XPS and XRD. Compositional analysis suggests replac ement of some cadmium by mercury in the CdxHg1-xTe films. Moreover, the inc orporation of mercury was also found to promote preferential orientation of (111) plane. Absorbance studies indicated a decrease in band gap from 1.47 eV for CdTe to 1.40 eV for Cd0.97Hg0.03Te. (C) 1999 Elsevier Science Ltd. All rights reserved.