The use of polymers other than divinylbenzene crosslinked polystyrene as su
pports in organic chemistry is discussed. Insoluble polymer alternatives to
DVB crosslinked polystyrene discussed include porous polyethylene supports
, polymer-supported functional colloids, micron and submicron-sized particl
es and hollow spheres and one-dimensional supports. Soluble polymers includ
ing polyethylene, poly(alkene oxide)s, polyacrylamides, and fluorinated acr
ylates are discussed along with thermomorphic strategies where liquid-liqui
d separation of a biphasic systems is used as a way to effect polymer recov
ery in systems that are monophasic on heating. (C) John Wiley & Sons, Inc.