Design of two channel flow cells for simultaneous determination of copper and iron

Citation
T. Sakai et al., Design of two channel flow cells for simultaneous determination of copper and iron, TALANTA, 49(5), 1999, pp. 989-996
Citations number
14
Categorie Soggetti
Spectroscopy /Instrumentation/Analytical Sciences
Journal title
TALANTA
ISSN journal
00399140 → ACNP
Volume
49
Issue
5
Year of publication
1999
Pages
989 - 996
Database
ISI
SICI code
0039-9140(19990809)49:5<989:DOTCFC>2.0.ZU;2-I
Abstract
Two compact double and serial flow cells were designed for simultaneous det ermination of trace copper and iron ions. 2-(5-Bromo-2-pyridylazo)-5-(N-pro pyl-N-sulfopropylamino)aniline(5-Br-PSAA) was used as a chromogenic reagent . 5-Br-PSAA reacted with Cu(II) and Fe(II) to form red chelate compounds an d did not react with Cu(I) and Fe(III). Based on these characteristics, a t hree-lines flow system using two channel flow cells was assembled for the s imultaneous determination of trace amounts of copper and iron and applied t o the assay of ground water. (C) 1999 Elsevier Science B.V. All rights rese rved.