Michael radical additions - Two short efficient syntheses of (+)-conocephalenol from (R)-pulegone

Authors
Cossy, J Bouzbouz, S Hakiki, A
Citation
J. Cossy et al., Michael radical additions - Two short efficient syntheses of (+)-conocephalenol from (R)-pulegone, TETRAHEDRON, 55(37), 1999, pp. 11289-11294
Citations number
15
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON
ISSN journal
00404020 → ACNP
Volume
55
Issue
37
Year of publication
1999
Pages
11289 - 11294
Database
ISI
SICI code
0040-4020(19990910)55:37<11289:MRA-TS>2.0.ZU;2-M
Abstract
Two short and efficient syntheses of (+)-conocephalenol are described from (R)-pulegone. The key steps are radical additions of tertiary radicals to e nones and an intramolecular aldol cyclization under acidic conditions. (C) 1999 Elsevier Science Ltd. All rights reserved.