The importance and usefulness of second-law analysis for evaluating and com
paring thermal energy storage (TES) systems in meaningful ways is discussed
. Some of the main thermodynamic factors to be considered in evaluating TES
performance are identified and described, including determining important
analysis quantities, obtaining appropriate measures of efficiency, pinpoint
ing losses, assessing the effects of stratification, and accounting for tim
e duration of storage. As an illustrative example, exergy analysis, a parti
cular type of second-law analysis, is applied to stratified TES systems in
order to evaluate the effects and benefits of thermal stratification. It is
concluded based on the results of the example that (i) the use of stratifi
cation in thermal storage designs should be considered as it increases the
exergy storage capacity of a thermal storage, and (ii) exergy analysis shou
ld be applied in the analysis and comparison of stratified thermal storage
systems.