Synthesis and electronic spectra of tricarbonylrhenium(I) chloride complexes with 9,10-phenanthrenequinone and 9,10-phenanthrenequinone diimine as acceptor ligands

Authors
Leirer, M Knor, G Vogler, A
Citation
M. Leirer et al., Synthesis and electronic spectra of tricarbonylrhenium(I) chloride complexes with 9,10-phenanthrenequinone and 9,10-phenanthrenequinone diimine as acceptor ligands, Z NATURFO B, 54(8), 1999, pp. 1039-1041
Citations number
20
Categorie Soggetti
Chemistry
Journal title
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES
ISSN journal
09320776 → ACNP
Volume
54
Issue
8
Year of publication
1999
Pages
1039 - 1041
Database
ISI
SICI code
0932-0776(199908)54:8<1039:SAESOT>2.0.ZU;2-J
Abstract
The complexes Re(L-L)(CO)(3)Cl with L-L = 9,10-phenanthrenequinone (PHQ) an d 9,10-phenanthrenequinone diimine (PHI) were prepared and characterized sp ectroscopically. Both compounds show intense Re(I) to L-L metal-to-ligand c harge transfer (MLCT) absorptions. In chloroform, the MLCT bands appear at 711 nm (L-L = PHQ) and 553 nm (L-L = PHI).