The optical characteristics of birefringent materials transmitting in
the near IR (0.9 - 2.5 mu m) are analyzed. Wollaston prisms with large
beam separation and virtually free from lateral chromatism - e.g. wit
h fields of view > 1 arcmin and image elongation < 0.3 '' - could be m
anufactured using AgGaS2 or LiYF4 (YLF). These materials are used for
non linear applications and may therefore find another interesting app
lication in IR focal plane instruments. From the optical point of view
the best material is AgGaS2 but YLF may be practically more convenien
t because of its lower refractive index (n similar to 1.45), better th
ermo-mechanical properties and lower price. New measurements of the tr
ansparency of Calcite at room and cryogenic temperatures are also pres
ented, these show significant absorption (similar or equal to 0.4 cm(-
1)) of the ordinary ray already at lambda = 2 mu m and very strong ban
ds (absorption coefficient a > 3 cm(-1)) beyond 2.25 mu m. The absorpt
ion does not decrease significantly when the crystals is cooled, CaCO3
should not be therefore used in instruments working beyond 2.0 mu m.