Rk. Nesbet, QUANTITATIVE THEORY AND ACCURATE EXPERIMENTS - LOW-ENERGY-ELECTRON SCATTERING BY HE AND H-2 AS CASE-STUDIES, Australian journal of physics, 50(3), 1997, pp. 473-482
Accurate low-energy electron scattering data are needed in many fields
of physics. However, accurate experiments are difficult to design and
to carry out. By 1967 low-energy electron-He cross sections had been
measured by two different techniques, designed to provide accurate dat
a. Unfortunately, the data differed by amounts well outside the estima
ted error bars. Despite the relative simplicity of the He atom, decisi
ve theoretical calculations on the e-He system could not be done with
methods available in 1967. After a decade of development of theoretica
l methodology it became possible in 1979 to carry out calculations wit
h absolute estimates of residual error limits. The results were found
to agree closely with the momentum transfer cross section deduced from
electron swarm data and with recent beam data by improved techniques,
but were inconsistent with the original beam data of 1965. More recen
tly, a similar conflict exists between data measured for electron-impa
ct vibrational excitation of the hydrogen molecule by electron swarm a
nd beam techniques. This conflict has persisted despite great progress
in beam scattering techniques and in theoretical methods. A brief rev
iew of the relevant electron scattering theory will be given.