Chemically deposited copper oxide thin films: structural, optical and electrical characteristics

Thin films of copper oxide with thickness ranging from 0.05-0.45 mu m were deposited on microscope glass slides by successively dipping them for 20 s each in a solution of 1 M NaOH and then in a solution of copper complex. Te mperature of the NaOH solution was varied from 50-90 degrees C, while that of the copper solution was maintained at room temperature. X-ray diffractio n patterns showed that the films, as prepared, are of cuprite structure wit h composition Cu2O. Annealing the films in air at 350 degrees C converts th ese films to CuO. This conversion is accompanied by a shift in the optical band gap from 2.1 eV (direct) to 1.75 eV (direct). The films show p-type co nductivity, similar to 5 X 10(-4) Omega(-1) cm(-1)for a film of thickness 0 .15 mu m. Electrical conductivity of this film increases by a factor of 3 w hen illuminated with 1 kW m(-2) tungsten halogen radiation. Annealing in a nitrogen atmosphere at temperatures up to 400 degrees C does not change the composition of the films. However, the conductivity in the dark as well as the photoconductivity of the film increases by an order of magnitude. The electrical conductivity of the CuO thin films produced by air annealing at 400 degrees C, is high, 7 X 10(-3) Omega(-1) cm(-1). These films are also p hotoconductive. (C) 1999 Elsevier Science B.V. All rights reserved.