Rs. Brusa et al., Microstructural analysis of hard amorphous carbon films deposited with high-energy ion beams, APPL SURF S, 150(1-4), 1999, pp. 202-210
Hard amorphous carbon films produced using high-energy (ca. 30 keV) ion bea
m deposition of CH3+ and CH4+ an silicon wafers, have been investigated by
Positron Annihilation Spectroscopy (PAS), the results are correlated with R
aman Spectroscopy and Electrical Resistivity measurements. The microstructu
ral modifications of the films as a function of the annealing temperature i
n the 300-600 degrees C range have been studied. The evolution of the fract
ions of sp(2) and sp(3) bonds is described and related to the changes of th
e open volume defect distribution and the graphitization process. (C) 1999
Elsevier Science B.V. All rights reserved.