Deprotonation of low-spin mononuclear iron(III)-hydroperoxide complexes give transient blue species assigned to high-spin iron(III)-peroxide complexes

Authors
Jensen, KB McKenzie, CJ Nielsen, LP Pedersen, JZ Svendsen, HM
Citation
Kb. Jensen et al., Deprotonation of low-spin mononuclear iron(III)-hydroperoxide complexes give transient blue species assigned to high-spin iron(III)-peroxide complexes, CHEM COMMUN, (14), 1999, pp. 1313-1314
Citations number
11
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
14
Year of publication
1999
Pages
1313 - 1314
Database
ISI
SICI code
1359-7345(19990721):14<1313:DOLMIC>2.0.ZU;2-9
Abstract
Purple iron(III)-hydroperoxide complex ions [Fe(Rtpen)(eta(1)-OOH)](2+) can be reversibly deprotonated to give transient blue species showing spectros copic properties consistent with iron(III)-peroxide complexes; a novel ferr yl species is produced in MS/MS experiments with the iron(III) hydroperoxid e ion.