X-ray structure and theoretical studies of RuH2(eta(2),H-2)(eta(2)-H-SiPh3)(PCy3)(2), a complex with two different eta(2)-coordinated sigma bonds

Authors
Hussein, K Marsden, CJ Barthelat, JC Rodriguez, V Conejero, S Sabo-Etienne, S Donnadieu, B Chaudret, B
Citation
K. Hussein et al., X-ray structure and theoretical studies of RuH2(eta(2),H-2)(eta(2)-H-SiPh3)(PCy3)(2), a complex with two different eta(2)-coordinated sigma bonds, CHEM COMMUN, (14), 1999, pp. 1315-1316
Citations number
23
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
14
Year of publication
1999
Pages
1315 - 1316
Database
ISI
SICI code
1359-7345(19990721):14<1315:XSATSO>2.0.ZU;2-U
Abstract
Weak interactions between the silicon and the hydrides are responsible for the stabilization of the title complex bearing two different coordinated si gma-bonds, (eta(2)-H-2) and (eta(2)-H-SiPh3).