Mg-0-promoted selective C-F bond cleavage of trifluoromethyl ketones: a convenient method for the synthesis of 2,2-difluoro enol silanes

Authors
Amii, H Kobayashi, T Hatamoto, Y Uneyama, K
Citation
H. Amii et al., Mg-0-promoted selective C-F bond cleavage of trifluoromethyl ketones: a convenient method for the synthesis of 2,2-difluoro enol silanes, CHEM COMMUN, (14), 1999, pp. 1323-1324
Citations number
18
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
14
Year of publication
1999
Pages
1323 - 1324
Database
ISI
SICI code
1359-7345(19990721):14<1323:MSCBCO>2.0.ZU;2-Y
Abstract
2,2-Difluoro enol silyl ethers were readily prepared by Mg-0 promoted selec tive defluorination of trifluoromethyl ketones in the presence of TMSCl, wh ich involves C-F bond cleavage.