Green chemistry - The sonochemical approach

Although the applications of ultrasound have long been known in both indust ry and academy, the "green" value of the non-hazardous acoustic radiation h as been recognised by synthetic and environmental chemists only recently. T he chemical and physical effects of ultrasound arise from the cavitational collapse which produce extreme conditions locally and thus induce the forma tion of chemical species not easily attained under conventional conditions, driving a particular radical reactivity. This rationale, accessible in a n on-mathematical manner, anticipates the advantages of using this technology in a variety of processes that include milder reactions with improved yiel ds and selectivities, easy generation of reactive species and catalysts or replacement of hazardous reagents. Sonication enables the rapid dispersion of solids, decomposition of organics including biological components, as we ll as the formation of porous materials and nanostructures. This review sum marises how ultrasound can be harnessed to develop an alternative and mild chemistry, which parallels the ability of acoustic waves to induce homolyti c bond cleavage.