Jm. Arandes et al., Kinetics of gaseous product formation in the coke combustion of a fluidized catalytic cracking catalyst, IND ENG RES, 38(9), 1999, pp. 3255-3260
Combustion of the coke deposited on a commercial catalytic cracking catalys
t is studied by differential scanning calorimetry. The conditions of the in
dustrial operation in a fluidized catalytic cracking unit causing deactivat
ion (feed, contact time, and temperature, C/O ratio) and those used for reg
eneration (catalyst stripping and temperature) have been reproduced. Combus
tion heat of coke is strongly dependent on combustion temperature and on de
activation severity (reaction conditions). Kinetic equations for the format
ion of gaseous combustion products, CO, CO2, and H2O, have been determined,
which are useful in the design of industrial regenerators.