Selective CO2 separation from CO2-N-2 mixtures by immobilized carbonate-glycerol membranes

Separation of carbon dioxide from a humid mixture of CO2-N-2 through membra nes containing immobilized solutions of Na2CO3-glycerol in porous and hydro philic poly(vinylidene fluoride) (PVDF) substrate was experimentally studie d for use as a venting membrane in space-walk applications. The effects of Na2CO3 concentration, CO2 partial pressure, and feed stream relative humidi ty (RH) were investigated. The carbonate concentration was in the range of 0-4.0 mol/dm(3). The feed gas RH range was 49-100%; the sweep gas was dry h elium. CO2 partial pressure (p(CO2,f)) range was 0.007-0.77 arm. Addition o f Na2CO3 increased the CO2 permeability drastically at lower carbonate conc entrations; at higher Na2CO3 concentrations, this permeability increase is partly compromised by increased solution viscosity and salting-out effect. N-2 permeability coefficient decreased with an increase in Na2CO3 concentra tion. Very high CO2/N-2 selectivities were observed at high Na2CO3 concentr ations. Higher CO2/N-2 selectivities were observed at lower CO2 partial pre ssure differentials. Steady-state water content in the hygroscopic immobili zed liquid membrane (ILM) increases with an increase in feed stream RH. The water content in the ILM considerably affects its viscosity and the effect ive concentration of the carriers in the ILM; those factors determine the p ermeation performances of the ILM. Generally, lower permeances and greater CO2/N-2 selectivity values were observed at lower feed stream RHs. When the feed RH = 50.7%, P-CO2,P-f = 0.007 atm and the Na2CO3 concentration was 1. 0 mol/dm(3); the separation factor alpha(CO2/N-2) observed was 3440. Prolon ged runs lasting 14 days showed that the ILM permeation performances were q uite stable. The ILMs were also found to be stable when challenged with fee d streams of very low RHs.