The first hydrogen bonded anionic phosphates exhibiting sulfur donor coordination

Authors
Chandrasekaran, A Sood, P Day, RO Holmes, RR
Citation
A. Chandrasekaran et al., The first hydrogen bonded anionic phosphates exhibiting sulfur donor coordination, INORG CHEM, 38(18), 1999, pp. 3952
Citations number
33
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY
ISSN journal
00201669 → ACNP
Volume
38
Issue
18
Year of publication
1999
Database
ISI
SICI code
0020-1669(19990906)38:18<3952:TFHBAP>2.0.ZU;2-0
Abstract
We have synthesized and structurally characterized the first anionic phosph ates undergoing sulfur donor action in the presence of hydrogen bonding. As a consequence, these phosphates increase their coordination geometry towar d a trigonal bipyramid. It is suggested that such action may occur at activ e sites of phosphoryl transfer enzyme containing anionic phosphate substrat es.