Stereoselective synthesis of tetraalkyl cyclobutene-1,2,3,4-tetracarboxylates. Synthesis of tetraalkyl (Z,Z)-buta-1,3-diene-1,2,3,4-tetracarboxylates

Citation
I. Yavari et F. Nourmohammadian, Stereoselective synthesis of tetraalkyl cyclobutene-1,2,3,4-tetracarboxylates. Synthesis of tetraalkyl (Z,Z)-buta-1,3-diene-1,2,3,4-tetracarboxylates, J CHEM R-S, (8), 1999, pp. 512-513
Categorie Soggetti
Chemistry
Journal title
JOURNAL OF CHEMICAL RESEARCH-S
ISSN journal
03082342 → ACNP
Issue
8
Year of publication
1999
Pages
512 - 513
Database
ISI
SICI code
0308-2342(199908):8<512:SSOTC>2.0.ZU;2-B
Abstract
Tetraalkyl cyclobutene-1,2,3,4-tetracarboxylates, prepared by intramolecula r Wittig reaction between a vinylphosphonium salt and diethyl 2-oxobutanedi oate, undergo electrocyclic ring-opening reactions, in boiling toluene, to produce highly electron-deficient 1,3-dienes.