Gj. Hwang et al., Hydrogen separation in H-2-H2O-HI gaseous mixture using the silica membrane prepared by chemical vapor deposition, J MEMBR SCI, 162(1-2), 1999, pp. 83-90
Hydrogen separation in H-2-H2O-HI gaseous mixture using the silica membrane
prepared by CVD was evaluated aiming at the application for hydrogen iodid
e decomposition in the thermochemical IS process. Porous alumina tubes havi
ng pore size of 100 nm (M1) and 10 nm (M2) were modified by chemical vapor
deposition using tetraethoxysilane as the Si source. Single-component perme
ance to He, H-2, and N-2 was measured at 300-600 degrees C. Hydrogen permea
nce of the modified membranes at a permeation temperature of 600 degrees C
was about 6 x 10(-9) mol/Pa m(2) s. H-2/N-2 selectivities at 600 degrees C
were 5.2 and 160 for M1 and M2 membrane, respectively. Separation experimen
ts of a H-2-H2O-HI mixture using the modified membranes were carried out at
300-600 degrees C. Hydrogen permeances were almost the same as the single-
component permeances, whereas HI permeances were below 1 x 10(-11) mol/Pa m
(2) s. The hydrogen permeances were not changed after one day exposure in a
mixture of H-2-H2O-HI with a molar composition of 0.23:0.65:0.12 at 450 de
grees C. (C) 1999 Elsevier Science B.V. All rights reserved.