Mossbauer effect studies on alkali tris(maleato) ferrates(III)

Authors
Randhawa, BS Sweety, KJ
Citation
Bs. Randhawa et Kj. Sweety, Mossbauer effect studies on alkali tris(maleato) ferrates(III), J RAD NUCL, 241(3), 1999, pp. 675-677
Citations number
12
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY
ISSN journal
02365731 → ACNP
Volume
241
Issue
3
Year of publication
1999
Pages
675 - 677
Database
ISI
SICI code
0236-5731(199909)241:3<675:MESOAT>2.0.ZU;2-K
Abstract
Mossbauer spectra of alkali tris(maleato) ferrates(III), i.e., M-3[Fe(C2H2C O4)(3)] . nH(2)O [M = Li, Na, K, Cs] at 300 K display a doublet. The Mossba uer parameters indicate these complexes to be high spin with octahedral sym metry. The isomer shift shows a decreasing trend with the increase in elect ronegativity/polarizing power of the substituent cation (Li+, Na+, K+, Cs+) . A linear correlation between isomer shift values and the (Fe-O) stretchin g frequencies has also been observed.