N-dodecanoylpyrrolidine as a new extractant for uranyl(II) and nitric acidin toluene

Authors
Han, JT Shao, H Zhu, JK Bao, BR Cao, FQ Wu, ZM
Citation
Jt. Han et al., N-dodecanoylpyrrolidine as a new extractant for uranyl(II) and nitric acidin toluene, J RAD NUCL, 241(3), 1999, pp. 679-681
Citations number
4
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY
ISSN journal
02365731 → ACNP
Volume
241
Issue
3
Year of publication
1999
Pages
679 - 681
Database
ISI
SICI code
0236-5731(199909)241:3<679:NAANEF>2.0.ZU;2-C
Abstract
N-dodecanoylpyrrolidine (DOPOD) was synthesized and used for the extraction of nitric acid and uranyl(VI) ions from nitric media in toluene. The effec ts of nitric acid concentration, extractant concentration, temperature, sal ting-out agent (LiNO3) have been studied. The main adduct of DOPOD and HNO3 is HNO3. DOPOD. The complex formation of uranyl(VI) ion, nitrate ion and D OPOD (UO2(NO3)(2). 2DOPOD) as extracted species are further confirmed by IR spectra and the values of thermodynamic parameters have also been calculat ed.