Thermochemistry of binding of lead(II) and cadminm(II) by saccharides in aqueous solution

Authors
Mihalick, JE Griffiths, WP Muten, JE Olson, TA Hein, JB
Citation
Je. Mihalick et al., Thermochemistry of binding of lead(II) and cadminm(II) by saccharides in aqueous solution, J SOL CHEM, 28(8), 1999, pp. 1019-1030
Citations number
31
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF SOLUTION CHEMISTRY
ISSN journal
00959782 → ACNP
Volume
28
Issue
8
Year of publication
1999
Pages
1019 - 1030
Database
ISI
SICI code
0095-9782(199908)28:8<1019:TOBOLA>2.0.ZU;2-1
Abstract
Solution calorimetry was used to determine enthalpies and stability constan ts for binding of lead(II) or cadmium(II) by galacturonic acid and several monosaccharides in aqueous solution. New values for enthalpies of solution in water are reported for galacturonic acid and maltose monohydrate. The in teraction of water solvent with the reactants is the largest factor in the binding process.