Activity coefficients for the system HCl+GaCl3+H2O from 5 to 55 degrees C

Authors
Roy, RN Roy, LN Gregory, DR Kiefer, SA Das, B Pitzer, KS
Citation
Rn. Roy et al., Activity coefficients for the system HCl+GaCl3+H2O from 5 to 55 degrees C, J SOL CHEM, 28(7), 1999, pp. 933-947
Citations number
30
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF SOLUTION CHEMISTRY
ISSN journal
00959782 → ACNP
Volume
28
Issue
7
Year of publication
1999
Pages
933 - 947
Database
ISI
SICI code
0095-9782(199907)28:7<933:ACFTSH>2.0.ZU;2-Y
Abstract
Activity coefficients for HCl in HCl + GaCl3 + H2O at eleven different temp eratures from 5 to 55 degrees C have been determined at total experimental ionic strengths from 0.01 to 3.0 mol-kg-l using a cell of the type: Pt; H-2(g, 1 atm)\HCl(m(A)) + GaCl3(m(B))\AgCl, Ag (A) The results for the 770 experimental emf data points have been used to dete rmine the variation of the activity coefficients of HCl with the change in molality of GaCl3 in the solution. It is found that the linear form of Harn ed's rule is not obeyed for this system.