Procedure for the determination of redox potentials of chemically (and electrochemically) irreversible inorganic redox couples from spectroscopic data

Authors
Sanchez, F Perez-Tejeda, P Perez, F Lopez-Lopez, M
Citation
F. Sanchez et al., Procedure for the determination of redox potentials of chemically (and electrochemically) irreversible inorganic redox couples from spectroscopic data, J CHEM S DA, (17), 1999, pp. 3035-3039
Citations number
33
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS
ISSN journal
03009246 → ACNP
Issue
17
Year of publication
1999
Pages
3035 - 3039
Database
ISI
SICI code
0300-9246(1999):17<3035:PFTDOR>2.0.ZU;2-P
Abstract
A procedure for the estimation of the redox potentials of chemically (or el ectrochemically) irreversible couples based on optical measurements and on the Marcus and Hush equations has been proposed and tested through the dete rmination of redox potentials of different Co(NH3)(5)L3+/2+ redox couples. The results are in agreement with the expectations based on the reactivity of these complexes.