Effect of mechanical grinding under argon and hydrogen atmospheres on structural and hydriding properties of LaNi5

Effect of mechanical grinding (MG) under argon and hydrogen atmospheres on structural and hydriding properties were investigated in detail. In MG-LaNi 5 under argon atmosphere, the grain size reaches similar to 20 nm for MG ti mes of 60 min and almost remains unchanged for more longer MG times. The pr essure-composition isotherm (P-C) in LaNi5 at room temperature indicates an enhancement of hydrogen solubility, a lowering of plateau pressure and a n arrowing of width of plateau by MG like FeTi but not Mg2Ni. On the other ha nd, in reactive MG (RMG)-LaNi5 under hydrogen atmosphere, a nanocrystallize d LaNi5H0.15 and amorphous phases coexist within 180 min of grinding time. For RMG times longer than 180 min, the nanostructured LaNi5H0.15 phase disa ppears and the remaining amorphous-LaNi5Hx dissociates into nano-Ni + LaNiy Hz (y<5). The P-C isotherm indicates no-plateau in the LaNi5 produced by RM G longer than 60 min and the hydriding properties become worse and worse wi th increasing RMG times. From these results, we conclude that the hydriding properties could not be improved by structural modifications in the system containing metals with strong affinity for hydrogen like rare earth metals .