Naturally occurring zircon sand was plasma spray coated on steel substrates
previously coated with NiCrAlY bond coat. The coatings were characterized
for their microstructure, chemical composition, thermal shock resistance, a
nd the nature of structural phases present, The as-sprayed coatings consist
ed of t-ZrO2 (major phase), m-ZrO2, ZrSiO4 (minor phases), and amorphous Si
O2. These coatings, when annealed at 1200 degrees C/1.44 x 10(4) s yielded
a ZrSiO4 phase as a result of the reaction between ZrO2 and SiO2, Dramatic
changes occurred in the characteristics of the coatings when a mixture of z
ircon sand and Y2O3 was plasma spray coated and annealed at 1400 degrees C/
1.44 x 10(4) s, The t-ZrO2 phase was completely stabilized, and these coati
ngs were found to have considerable potential for thermal barrier applicati
ons.