Local approximation for the Hartree-Fock exchange potential: A deformationapproach

Citation
O. Bokanowski et Nj. Mauser, Local approximation for the Hartree-Fock exchange potential: A deformationapproach, MATH MOD M, 9(6), 1999, pp. 941-961
Citations number
29
Categorie Soggetti
Mathematics
Journal title
MATHEMATICAL MODELS & METHODS IN APPLIED SCIENCES
ISSN journal
02182025 → ACNP
Volume
9
Issue
6
Year of publication
1999
Pages
941 - 961
Database
ISI
SICI code
0218-2025(199908)9:6<941:LAFTHE>2.0.ZU;2-Q
Abstract
We present a method for deriving local approximations of the exchange-term in the Hartree-Fock equation for a system of fermions interacting with a Co ulomb-force. Within our model, we give a justification of the Slater-approx imation where the exchange-term is replaced by the third root of the local density. Our approach is based on deformations, i.e. local scaling transfor mations of a constant density, combined with the "high density limit" of in finite number of particles.