Oxidative addition reactions of cyclic aryloxy-, amino- and chloro-phosphites and arsenites

Authors
Swamy, KCK Muthiah, C Kumaraswamy, S Said, MA
Citation
Kck. Swamy et al., Oxidative addition reactions of cyclic aryloxy-, amino- and chloro-phosphites and arsenites, P I A S-CH, 111(3), 1999, pp. 489-500
Citations number
23
Categorie Soggetti
Chemistry
Journal title
PROCEEDINGS OF THE INDIAN ACADEMY OF SCIENCES-CHEMICAL SCIENCES
ISSN journal
02534134 → ACNP
Volume
111
Issue
3
Year of publication
1999
Pages
489 - 500
Database
ISI
SICI code
0253-4134(199906)111:3<489:OAROCA>2.0.ZU;2-R
Abstract
Reaction of cyclic phosphites with 1,2-diketones and with diol/N-chlorodiis opropylamine has been studied. A large number of penta- and hexacoordinated phosphorus derivatives with varying ring sizes have been synthesized and s tructurally characterized. The reactivity of phosphites is compared with th at of arsenites and pentacoordinated phosphoranes. Several phosphonates tha t are important as synthetic reagents have been prepared by reacting cyclic phosphites with aldehydes.