This paper presents the novel method of using pigmented dielectric reflecto
rs to provide light trapping in thin-film silicon solar cells. This type of
reflecting material offers many potential advantages over specular metalli
c reflectors, including low cost, compatibility with high temperatures comm
on to solar cell processing, and high, broadband and diffuse reflectance, A
s this is the first time this concept is described, the basic theory of the
optical behavior of pigmented materials is presented by connecting the bas
ic material properties of pigment and medium to their light trapping benefi
t in thin silicon solar cells. Several general principles Lading to maximum
light-trapping benefit are identified and experimental evidence is present
ed corroborating these general principles. Light trapping is demonstrated i
n thin silicon solar cells with pigmented dielectric reflectors by measurem
ent and analysis of external quantum efficiency curves. Copyright (C) 1999
John Wiley & Sons, Ltd.