Supported ruthenium catalysts in hydrodechlorination of CCl2F2 (CFC-12)

Authors
Malinowski, A Juszczyk, W Bonarowska, M Wojciechowska, M Kowalczyk, Z Karpinski, Z
Citation
A. Malinowski et al., Supported ruthenium catalysts in hydrodechlorination of CCl2F2 (CFC-12), REACT KIN C, 68(1), 1999, pp. 53-60
Citations number
14
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
REACTION KINETICS AND CATALYSIS LETTERS
ISSN journal
01331736 → ACNP
Volume
68
Issue
1
Year of publication
1999
Pages
53 - 60
Database
ISI
SICI code
0133-1736(199909)68:1<53:SRCIHO>2.0.ZU;2-5
Abstract
Active carbon- and MgF2-supported ruthenium catalysts characterized by a co mparable metal dispersion were investigated in CCl2F2 hydrodechlorination. Ruthenium, especially when supported on carbon, exhibits a considerable sel ectivity to CHClF2. This propensity and a noticeable activity towards C-2-p roducts differentiate ruthenium from palladium catalysts.