SYNTHESIS AND CRYSTAL-STRUCTURE OF LAMINO(DI-TERT-BUTYL)SILICENIO-TRICHLOROALUMINATE, (ME3C)(2)SI=NCME3-CENTER-DOT-ALCL3, AND DIMETHYLAZOMETHINE ALUMINUM TRICHLORIDE, ME2C=NH-CENTER-DOT-ALCL3

Authors
KLINGEBIEL U NOLTEMEYER M SCHMIDT HG SCHMIDTBASE D
Citation
U. Klingebiel et al., SYNTHESIS AND CRYSTAL-STRUCTURE OF LAMINO(DI-TERT-BUTYL)SILICENIO-TRICHLOROALUMINATE, (ME3C)(2)SI=NCME3-CENTER-DOT-ALCL3, AND DIMETHYLAZOMETHINE ALUMINUM TRICHLORIDE, ME2C=NH-CENTER-DOT-ALCL3, Chemische Berichte, 130(6), 1997, pp. 753-755
Citations number
15
Categorie Soggetti
Chemistry
Journal title
Chemische Berichte → ACNP
ISSN journal
00092940
Volume
130
Issue
6
Year of publication
1997
Pages
753 - 755
Database
ISI
SICI code
0009-2940(1997)130:6<753:SACOL>2.0.ZU;2-4
Abstract
Lithiated tert-butylaminofluorosilanes react with aluminium trichlorid e in ether, eliminating LiF to give AlCl3 adducts of iminosilanes - am inosiliceniotrichloroaluminates (R2Si-NCMe3 . AlCl3), which thermally form the dimethylazomethine-aluminium trichloride, Me2C=NH . AlCl3.